Effect of fluorine–oxygen mixed gas treated graphite fibers on electrochemical behaviors of platinum–ruthenium nanoparticles toward methanol oxidation

In the present study, graphite fibers (GFs) were treated with fluorine–oxygen mixed gas with changing gas treatment temperatures to study the effect of surface modification. Treated GFs-supported platinum (Pt)/ruthenium (Ru) catalysts were prepared to check the influence of gas treatment on electroactivity of metal catalysts. The crystalline size and the surface compositions of the carbon-supported catalysts were determined by XRD and XPS, respectively. Electrochemical properties of the electrocatalysts were analyzed by cyclic voltammetry (CV) measurements. When gas-treated GFs were used as a catalyst support, the current density for a methanol oxidation was greater than that of pristine catalyst; meaning the treated GFs-supported catalysts had a higher electroactivity. These results were in agreement with CV results that confirmed the greater effective electrochemical surface area for a hydrogen adsorption–desorption reaction of catalysts, which was originated from smaller particle size.