Title of article
Control of hydroxyl group conformation by the pentafluorosulfanyl group
Author/Authors
Savoie، نويسنده , , Paul R. and Welch، نويسنده , , Jan M. and Higashiya، نويسنده , , Seiichiro and Welch، نويسنده , , John T.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
1
To page
5
Abstract
The unique properties of the pentafluorosulfanyl group lead to previously unrecognized interactions with neighboring hydroxyl groups that differ substantially from those of alkyl or fluoroalkyl chains. Computational methods (B3LYP/6-31++G(d,p)) were utilized to assess the geometries and barriers to rotation. Conformational control was derived primarily from restricted rotation about the SF5CCOH bond.
Keywords
Rotational barrier , Fluoroalkyl group , Conformation , Pentafluorosulfanyl group , alcohol
Journal title
Journal of Fluorine Chemistry
Serial Year
2013
Journal title
Journal of Fluorine Chemistry
Record number
1611976
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