Title of article
Hydrodefluorinations of trifluorotoluenes by LiAlH4 and TiCl4
Author/Authors
Akiyama، نويسنده , , Takahiko and Atobe، نويسنده , , Kohei and Shibata، نويسنده , , Michiko and Mori، نويسنده , , Keiji، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
3
From page
81
To page
83
Abstract
In the presence of 2 mol% of TiCl4, α,α,α-trifluorotoluene derivatives were reduced with LiAlH4 to furnish toluene derivatives in high yields. Selective reduction of bis(trifluoromethyl)benzene derivative is effected. The difference of the reactivity between TiCl4 and NbCl5 is also discussed.
Keywords
TiCl4 , Hydrodefluorination , Reduction , Trifluorotoluenes
Journal title
Journal of Fluorine Chemistry
Serial Year
2013
Journal title
Journal of Fluorine Chemistry
Record number
1612045
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