Title of article
Photooxidation of bis(diethyldithiocarbamato)dicarbonyliron(II) in chloroform
Author/Authors
Kunkely، نويسنده , , Horst and Vogler، نويسنده , , Arnd، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
3
From page
289
To page
291
Abstract
The complex FeII(et2dtc)2(CO)2 with et2dtc− (diethyldithiocarbamate) in CHCl3 undergoes a photooxidation to FeIII(et2dtc)2Cl with a quantum yield of φ=0.0015 at λirr=366 nm. It is suggested that this photoreaction originates from a (FeII→π∗ (et2dtc−)) metal-to-ligand charge transfer or ligand-field excited state.
Keywords
Electronic spectra , Photooxidation , Iron complexes , Iron–sulfur compounds
Journal title
Journal of Photochemistry and Photobiology:A:Chemistry
Serial Year
2003
Journal title
Journal of Photochemistry and Photobiology:A:Chemistry
Record number
1612514
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