Influence of growth temperature on the structure and thermodynamic parameters of barley starches

Barley starches grown at different temperatures were investigated using high sensitivity differential scanning microcalorimetry and X-ray diffraction. By applying physico-chemical approaches, thickness of crystalline lamellae, thermodynamic and structural characteristics (such as gelatinisation) of cooperative units and parameters characterising thermodynamic properties of crystal surfaces were determined. It was established that a difference of growth temperature experienced by plants during development does not lead to changes in the thickness of amylopectin crystalline lamellae and hence constituent double helix length. The role of defects in structural organisation of native barley starches is discussed. It is suggested that not all fatty acids necessarily form crystalline inclusion complexes.