Title of article
Is spin-orbit state branching in the photodissociation of CCl4 isotope specific?
Author/Authors
Maul، نويسنده , , Christof and Chichinin، نويسنده , , Alexey، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
3
From page
255
To page
257
Abstract
We have reinvestigated the ultraviolet photodissociation of CCl4 around 235 nm. The yield of spin-orbit state excited Cl*(2P1/2) atoms was found to be 0.26 ± 0.03, independently of the isotopic mass of the chlorine atom. No evidence of isotope specific Cl* yields was observed. Our results suggest that the previously reported isotope specificity in the photodissociation of CCl4 does not exist.
Keywords
Spin-orbit state branching , Carbon tetra chloride , Photodissociation
Journal title
Journal of Photochemistry and Photobiology:A:Chemistry
Serial Year
2007
Journal title
Journal of Photochemistry and Photobiology:A:Chemistry
Record number
1615385
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