Title of article
Mechanistic duality of the side-chain substitution in electrophilic aromatic nitration. Unexpected large difference in deuterium isotope effect kH/kD between the side-chain nitration and nitrooxylation of deuterated p-xylenes
Author/Authors
Nonoyama، نويسنده , , Nobuaki and Iwaya، نويسنده , , Masao and Suzuki، نويسنده , , Hitomi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
229
To page
233
Abstract
A large difference in deuterium kinetic isotope effect observed between the side-chain nitration and nitrooxylation of deuterated p-xylenes, 1,4-(CH3)(CD3)C6H4 and 1,4-(CD3)2C6D4, suggests the operation of different mechanisms for these two types of side-chain substitution.
Keywords
isotope effects , Nitration , nitrogen oxides , nitrous acid derivatives , Mechanisms
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1636010
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