Title of article
Expedient synthesis of (+)-trans-5-allylhexahydroindolizidin-3-one
Author/Authors
Potts، نويسنده , , Deirdre and Stevenson، نويسنده , , Paul J. and Thompson، نويسنده , , Norris، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
275
To page
278
Abstract
Treatment of the bicyclic iminium ion derived from 5-methoxyhexahydroindolizidin-3-one with allyltrimethylsilane gave exclusively the diastereoisomer in which the allyl group was axial. This substrate is a useful precursor to 5-propyl-3-alkylindolizidine alkaloids.
Keywords
pyroglutamate , 1 , 3-allylic strain , indolizidine , N-acyliminium ion
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1636029
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