Title of article
Total synthesis of (−)-eburnamonine and (+)-epi-eburnamonine from a chiral non-racemic 4,4-disubstituted γ-lactone
Author/Authors
Wee، نويسنده , , Andrew G.H and Yu، نويسنده , , Qing، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
587
To page
590
Abstract
The total synthesis of (−)-eburnamonine and (+)-epi-eburnamonine was successfully achieved using a key chiral non-racemic 4,4-disubstituted γ-lactone 4 that was prepared via the Rh(II) carbenoid mediated tertiary C–H insertion reaction of a chiral non-racemic diazomalonate 5.
Keywords
asymmetric synthesis , tertiary C–H , Insertion , rhodium(II) carbenoid
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1636168
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