• Title of article

    Total synthesis of (−)-eburnamonine and (+)-epi-eburnamonine from a chiral non-racemic 4,4-disubstituted γ-lactone

  • Author/Authors

    Wee، نويسنده , , Andrew G.H and Yu، نويسنده , , Qing، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    587
  • To page
    590
  • Abstract
    The total synthesis of (−)-eburnamonine and (+)-epi-eburnamonine was successfully achieved using a key chiral non-racemic 4,4-disubstituted γ-lactone 4 that was prepared via the Rh(II) carbenoid mediated tertiary C–H insertion reaction of a chiral non-racemic diazomalonate 5.
  • Keywords
    asymmetric synthesis , tertiary C–H , Insertion , rhodium(II) carbenoid
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1636168