• Title of article

    Rhodium-carbenoid-mediated intermolecular O–H insertion reactions: a dramatic additive effect. Application in the synthesis of an ascomycin derivative

  • Author/Authors

    Nelson، نويسنده , , Todd D and Song، نويسنده , , Zhiguo Jake and Thompson، نويسنده , , Andrew J. and Zhao، نويسنده , , Mangzhu and DeMarco، نويسنده , , Anthony and Reamer، نويسنده , , Robert A and Huntington، نويسنده , , Martha F and Grabowski، نويسنده , , Edward J.J and Reider، نويسنده , , Paul J، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    5
  • From page
    1877
  • To page
    1881
  • Abstract
    A catalyst system of Rh2(oct)4/DIPEA or TMU allows for the rapid construction of α-alkoxyketones from the corresponding α-diazo ketone and alcohol. This methodology was applied to the synthesis of immunoregulant 1.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1636598