Title of article
Palladium-catalyzed stereoselective C-glycosidation of unprotected enones derived from d-glucal with trimethylsilyl cyanide
Author/Authors
Hayashi، نويسنده , , Masahiko and Kawabata، نويسنده , , Hirotoshi and Shimono، نويسنده , , Satoshi and Kakehi، نويسنده , , Akikazu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
2591
To page
2594
Abstract
Acetylated and unprotected enones derived from d-glucal reacted with trimethylsilyl cyanide in the presence of a catalytic amount of a palladium compound in 1,4-addition fashion to afford the corresponding 3-keto-glycosyl cyanides in high yield and in high α-selectivity.
Keywords
palladium and compounds , enones , C-glycosidation
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1636898
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