Title of article
Efficient asymmetric selenomethoxylation and selenohydroxylation of alkenes with a new sulfur containing chiral diselenide
Author/Authors
Tiecco، نويسنده , , Marcello and Testaferri، نويسنده , , Lorenzo and Bagnoli، نويسنده , , Luana and Marini، نويسنده , , Francesca and Temperini، نويسنده , , Andrea and Tomassini، نويسنده , , Cristina and Santi، نويسنده , , Claudio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
3241
To page
3245
Abstract
The synthesis of a new chiral non-racemic sulfur containing diselenide is described. The electrophilic selenium reagent, produced from this diselenide by treatment with bromine and silver triflate, has been used to effect the selenomethoxylation and the selenohydroxylation of alkenes. These addition reactions occurred with good chemical yield and with high diastereoselectivities.
Keywords
chiral diselenides , asymmetric synthesis , selenomethoxylation , selenohydroxylation
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637304
Link To Document