Title of article
A new highly diastereoselective synthesis of epi-inositol from d-galactose
Author/Authors
Venerando Pistarà، نويسنده , , Venerando and Barili، نويسنده , , Pier Luigi and Catelani، نويسنده , , Giorgio and Corsaro *، نويسنده , , Antonino and D’Andrea، نويسنده , , Felicia and Fisichella، نويسنده , , Salvatore، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
3253
To page
3256
Abstract
The inosose derivative 3 was obtained with high stereoselectivity by intramolecular aldol condensation of the aldohexos-5-ulose derivative 2, and it was selectively reduced and debenzylated to give epi-inositol in high yield. The stereochemistry and the preferred conformations of compounds 3–7 were determined through 1D and 2D NMR experiments.
Keywords
intramolecular aldol condensations , Inositols , carbohydrates , Reduction
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637310
Link To Document