Title of article
Palladium-catalyzed kinetic resolution of racemic cyclic and acyclic allylic carbonates with sulfur nucleophiles
Author/Authors
Gais، نويسنده , , Hans-Joachim and Spalthoff، نويسنده , , Nicole and Jagusch، نويسنده , , Thomas and Frank، نويسنده , , Michael and Raabe، نويسنده , , Gerhard، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
3809
To page
3812
Abstract
A chiral Pd(0) complex bearing the Trost ligand in combination with S-nucleophiles effects the kinetic resolution of cyclic and acyclic allylic carbonates with excellent levels of enantioselectivity to give enantiomerically highly enriched allylic carbonates as well as allylic sulfones and sulfides. This method allows also for a new access to enantiopure cyclic allylic alcohols.
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637617
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