Title of article
Regioselective O-acylation of myo-inositol 1,3,5-orthoesters: the role of acyl migration
Author/Authors
Sureshan، نويسنده , , K.M and Shashidhar، نويسنده , , M.S، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
4185
To page
4188
Abstract
An efficient and general method for the preparation of 2-O-acylated derivatives of myo-inositol 1,3,5-orthoesters via isomerization of the corresponding 4(6)-O-acylated derivatives has been described. The isomerization involves a novel 1(axial)→3(equatorial) intramolecular acyl migration assisted by a metal ion.
Keywords
Acyl migration , chelation , Cyclitols , Inositol , Isomerization
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637798
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