Title of article
A sultone approach to the C(1)–C(18) moiety of pamamycin-607
Author/Authors
Bernsmann، نويسنده , , Heiko and Frِhlich، نويسنده , , Roland and Metz، نويسنده , , Peter، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
4347
To page
4351
Abstract
A highly advanced enantiomerically pure C(1)–C(18) precursor of the larger fragment of the macrodiolide pamamycin-607 has been synthesized. The stereotriad C(7)–C(9) between the two heterocyclic rings of the target was generated using a diastereoselective hydroboration controlled by minimization of allylic 1,3-strain.
Keywords
Diels–Alder reactions , sultones , Hydroboration , antibiotics
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637862
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