Title of article
Radical cleavage of a β-hydroxy azide: a reversal of regioselectivity in the oxidative fragmentation of hydroindoles
Author/Authors
Wipf، نويسنده , , Peter and Mareska، نويسنده , , David A.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
4723
To page
4727
Abstract
Treatment of hydroindole 17 with PhI(OAc)2/I2 leads to oxidative fragmentation of the β-hydroxy azide moiety and results in the exclusive formation of keto nitrile 18 via radical cleavage of the lateral ring C–C bond.
Keywords
regioselective oxidative fragmentation , hydroxy azide , keto nitrile
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638019
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