Title of article
Free radical addition to branched allylsilanes: stereoselective formation and elimination of β bromosilanes
Author/Authors
Porter، نويسنده , , Ned A. and Zhang، نويسنده , , Guiru and Reed، نويسنده , , Aimee D.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
5773
To page
5777
Abstract
Lewis acid-promoted free radical addition to 3-silyl-1-butenes occurs in good yield to give predominantly the cis-substituted alkene. The transfer reaction occurs by atom-transfer addition of the alkyl bromide precursor, an addition that occurs by Felkin–Anh control. Stereoselective anti elimination of the intermediate β-silylhalide gives the cis olefin.
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638294
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