Title of article
Electrochemical oxidation of 2,2,2-trifluoroethanol to trifluoroacetaldehyde 2,2,2-trifluoroethyl hemiacetal
Author/Authors
Shirai، نويسنده , , Kimihiro and Onomura، نويسنده , , Osamu and Maki، نويسنده , , Toshihide and Matsumura، نويسنده , , Yoshihiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
5873
To page
5876
Abstract
Electrochemical oxidation of 2,2,2-trifluoroethanol (1) gave trifluoroacetaldehyde 2,2,2-trifluoroethyl hemiacetal (2b), which was more reactive than commercially available trifluoroacetaldehyde ethyl hemiacetal (2a). The high reactivity of 2b was utilized, for example, for the facile synthesis of 1-furyl-2,2,2-trifluoroethanol (4) from furan.
Keywords
Electrochemistry , Oxidation , Fluorine and compounds , alcohols
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638315
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