Title of article
Synthesis and stereoselective aldol reaction of dihydroxyacetone derivatives
Author/Authors
Soo Kim، نويسنده , , Kwan and Don Hong، نويسنده , , Sung، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
5909
To page
5913
Abstract
Efficient synthetic methods for 1,3-di-O-benzyldihydroxyacetone (3) and 1,3-O-cyclohexylidenedihydroxyacetone (8) were developed. TiCl4-mediated aldol reaction of the silyl enol ether of 3 with aldehydes gave syn aldol products while the reaction of the silyl enol ether of 8 with aldehydes afforded anti aldol products.
Keywords
Enol ethers , Enolates , aldol reactions , diastereoselection
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638323
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