• Title of article

    Aziridination of 11-pregnene-3,20-dione using PhIN-Ses

  • Author/Authors

    Di Chenna، نويسنده , , Pablo H and Dauban، نويسنده , , Philippe and Ghini، نويسنده , , Alberto and Burton، نويسنده , , Gerardo and Dodd، نويسنده , , Robert H، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    5
  • From page
    7041
  • To page
    7045
  • Abstract
    The copper-catalyzed reaction of [N-(Ses)imino]phenyliodinane with 11-pregnene-3,20-dione gave the corresponding aziridine in 53% yield. The Ses protecting group could be conveniently removed using the TASF reagent. Furthermore, nucleophilic ring opening of the protected N-Ses-aziridine with thiophenol in the presence of a Lewis acid led to introduction of the thiophenol group at the α-12 position but, unexpectedly, concomitant loss of the Ses group to provide compound 10.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1638798

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1638798