Title of article
Tetraalkylammonium salt-based catalyst systems for directing Heck-type reactions. Arylation of allyltrimethylsilane
Author/Authors
Jeffery، نويسنده , , Tuyet، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
8445
To page
8449
Abstract
An appropriate selection of the [Pd/base/QX] catalyst systems allows one to direct at will the palladium-catalysed arylation of allyltrimethylsilane towards the formation of either (E)-1-aryl-3-(trimethylsilyl)-1-propene or 3-aryl-1-propene, by preventing or promoting efficiently the desilylation and the double bond migration.
Keywords
Ammonium salts , arylation , Heck reactions , palladium and compounds
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639578
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