Title of article
Vanadium-catalyzed stereoselective cyclodimerization of arylidene malononitrile in the presence of chlorosilane and zinc
Author/Authors
Zhou، نويسنده , , Longhu and Hirao، نويسنده , , Toshikazu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
8517
To page
8521
Abstract
A catalytic cyclodimerization of arylidene malononitriles proceeded diastereoselectively with reversible redox between vanadium and zinc in the presence of chlorotrimethylsilane. The reductive coupling reaction strongly depended on the co-reductant, additive, solvent, and substrate.
Keywords
diastereoselective cyclization , one-electron reduction , silylating reagent , Vanadium catalyst , co-reductant
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639627
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