• Title of article

    Conjugate intra- and intermolecular addition mediated by methoxide anion on polymeric support

  • Author/Authors

    Fava، نويسنده , , Cristiana and Galeazzi، نويسنده , , Roberta and Gonzalez-Rosende، نويسنده , , Eugenia Maria and Orena، نويسنده , , Mario، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    8577
  • To page
    8580
  • Abstract
    By treatment with methoxide anion on polymeric support (IRA 900), chiral β-oxo or β-sulphonylamides 2 bearing an α,β-unsaturated ester gave 3,4-disubstituted pyrrolidin-2-ones 3 as easily separable diastereomeric mixtures in good yield and moderate-to-good stereoselection. The polymeric reagent was also effective in promoting both intermolecular conjugate addition and alkylation reactions.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1639674