Title of article
A simple and scalable method to prepare 1-aza-5-chloro-5-stannabicyclo[3.3.3]undecane
Author/Authors
Yang، نويسنده , , Chunhua and Jensen، نويسنده , , Mark S and Conlon، نويسنده , , David A and Yasuda، نويسنده , , Nobuyoshi and Hughes، نويسنده , , David L، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
8677
To page
8681
Abstract
A simple and scalable method for the preparation of a potentially versatile organostannane, 1-aza-5-chloro-5-stannabicyclo[3.3.3]undecane (1), is described. Stannane 1 was prepared by the disproportionation of N(CH2CH2CH2SnBu3)3 and SnCl4 at 70–100°C. This reaction requires the addition of water or an alcohol to proceed efficiently. Under typical conditions, 1 was isolated in 50–55% yield after a simple acid/base extraction sequence.
Keywords
Bicyclic heterocyclic compounds , tin and compounds , Coupling reagents
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639743
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