Title of article
Radical-chain redox rearrangement of cyclic benzylidene acetals to benzoate esters in the presence of thiols
Author/Authors
Roberts، نويسنده , , Brian P and Smits، نويسنده , , Teika Pakalns، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
137
To page
140
Abstract
Cyclic benzylidene acetals derived from 1,2- and 1,3-diols undergo an efficient ring-opening redox rearrangement to give benzoate esters in the presence of a peroxide initiator and a thiol, which acts as a polarity-reversal catalyst to promote the radical-chain reaction.
Keywords
radicals and radical reactions , Catalysis , thiols , Diols , Rearrangements , carbohydrates
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1640958
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