Title of article
From allylic alcohols to aldols via a novel, tandem isomerization–condensation catalyzed by Fe(CO)5
Author/Authors
Crévisy، نويسنده , , Christophe and Wietrich، نويسنده , , Marina and Le Boulaire، نويسنده , , Virginie and Uma، نويسنده , , Ramalinga and Grée، نويسنده , , René، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
395
To page
398
Abstract
Allylic alcohols react with aldehydes, in the presence of catalytic amounts of Fe(CO)5 and under irradiation, to give mainly aldol products. A small amount of ketone resulting from the classical isomerization process is also isolated. This new aldol-type reaction is a complete atom economy process occurring under neutral conditions.
Keywords
aldols , Catalysts , Transition metals
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1641168
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