Title of article
Classical and non-classical secondary orbital interactions and Coulombic attraction in the regiospecific dimerization of acrolein
Author/Authors
Toma، نويسنده , , Lucio and Quadrelli، نويسنده , , Paolo and Caramella، نويسنده , , Pierluigi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
731
To page
733
Abstract
Non-classical (bridging) and classical (Woodward–Hoffmann) secondary orbital interactions as well as a favourable electrostatic interaction are involved in the stabilization of the two lowest transition passes of the acrolein dimerization. The heteroatoms provide anchimeric assistance to the hetero Diels–Alder reaction through a neighbouring-group mechanism.
Keywords
secondary orbital interactions , dimerization , Acrolein
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1641439
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