• Title of article

    Carbamoylsilanes from the in situ metalation–silylation of a formamide

  • Author/Authors

    Cunico، نويسنده , , Robert F، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    1423
  • To page
    1425
  • Abstract
    In situ treatment (−78°C) of N-methoxymethyl–N-methylformamide and chlorotrimethylsilane with LDA affords synthetically useful yields of the carbamoylsilane. The latter undergoes silyl group exchange at 145°C in the presence of a chlorosilane and CsF.
  • Keywords
    carbamoylsilanes , carbamoyllithium , silyl group exchange , metalation–silylation
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1642045