Title of article
Carbamoylsilanes from the in situ metalation–silylation of a formamide
Author/Authors
Cunico، نويسنده , , Robert F، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
1423
To page
1425
Abstract
In situ treatment (−78°C) of N-methoxymethyl–N-methylformamide and chlorotrimethylsilane with LDA affords synthetically useful yields of the carbamoylsilane. The latter undergoes silyl group exchange at 145°C in the presence of a chlorosilane and CsF.
Keywords
carbamoylsilanes , carbamoyllithium , silyl group exchange , metalation–silylation
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1642045
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