Title of article
Regio- and enantioselective carbolithiation of non-activated CC bonds
Author/Authors
Norsikian، نويسنده , , Stéphanie and Baudry، نويسنده , , Monique and Normant، نويسنده , , Jean F، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
6575
To page
6578
Abstract
Primary alkyllithiums in the presence of (−)-sparteine, add to terminal conjugated dienes. They also add to 2,4-pentadien-1-ols if they are substituted on C(5), and give rise to allyllithium intermediates. 2-Alkyl-alkan-1-ols have thus been prepared with eeʹs up to 74%.
Keywords
Carbometalation , (?)-sparteine , Enantioselection
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1642302
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