• Title of article

    Regio- and enantioselective carbolithiation of non-activated CC bonds

  • Author/Authors

    Norsikian، نويسنده , , Stéphanie and Baudry، نويسنده , , Monique and Normant، نويسنده , , Jean F، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    6575
  • To page
    6578
  • Abstract
    Primary alkyllithiums in the presence of (−)-sparteine, add to terminal conjugated dienes. They also add to 2,4-pentadien-1-ols if they are substituted on C(5), and give rise to allyllithium intermediates. 2-Alkyl-alkan-1-ols have thus been prepared with eeʹs up to 74%.
  • Keywords
    Carbometalation , (?)-sparteine , Enantioselection
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1642302