Title of article
Highly diastereoselective hydrophosphonylation of cyclic imines using BINOL as source of chirality
Author/Authors
Imre Schlemminger، نويسنده , , Imre and Lützen، نويسنده , , Arne and Willecke، نويسنده , , Andreas and Maison، نويسنده , , Wolfgang and Koch، نويسنده , , Rainer and Saak، نويسنده , , Wolfgang and Martens، نويسنده , , Jürgen، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
7285
To page
7288
Abstract
The first highly diastereoselective (dr up to >95:5) hydrophosphonylation of heterocyclic imines by a chiral phosphorus nucleophile is introduced. Addition of binaphthol ester of phosphorus acid towards BF3-activated 3-thiazolines gives the corresponding (aR*,4R*)-4-thiazolidinylphosphonates almost exclusively as elucidated by X-ray analysis.
Keywords
thiazolines , phosphorus acids and derivatives , diastereoselection
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1642480
Link To Document