• Title of article

    Synthesis and redox behavior of dialkylated dicobalt complexes having two discrete salen units

  • Author/Authors

    Shimakoshi، نويسنده , , Hisashi and Goto، نويسنده , , Akihiro and Tachi، نويسنده , , Yoshimitsu and Naruta، نويسنده , , Yoshinori and Hisaeda، نويسنده , , Yoshio، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    1949
  • To page
    1951
  • Abstract
    Novel dialkylated dicobalt complexes with two discrete salen units have been synthesized and characterized by UV–vis, NMR, and ESI-mass spectroscopies as well as elemental analyses. Redox behavior of the complexes was investigated by means of cyclic voltammetry and ESR spin-trapping techniques. The results indicate that cobaltcarbon bonds cleave homolytically to produce the radical species during the electrolysis.
  • Keywords
    cobalt?carbon bond , vitamin B12 model complex , dinucleating ligand , radical species
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1643615

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1643615