Title of article
Addition of NOCl to cyclic vinylsilanes: an unexpected reversal of regiochemistry
Author/Authors
M. Narendra Mallya، نويسنده , , M and Nagendrappa، نويسنده , , Gopalpur and Shashidhara Prasad، نويسنده , , J and Sridhar، نويسنده , , M.A and Lokanath، نويسنده , , N.K and Begum، نويسنده , , N.S، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
2565
To page
2568
Abstract
NOCl adds to cyclic vinylsilanes in a syn manner with NO+ bonding to the β-carbon and Cl− to the α-carbon, which is a reversal of the regiochemistry expected from the β-silicon effect. The adducts dimerize to a single diastereomer containing enantiomeric pairs and/or give secondary products on further reaction.
Keywords
NOCl , vinylsilanes , silylated diazene dioxides , nitrososilanes
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1644029
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