Title of article
Allenes from ynals
Author/Authors
Tius، نويسنده , , Marcus A and Pal، نويسنده , , Subrata K، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
2605
To page
2608
Abstract
Hydrosilylation of ynals with triethylsilane is catalyzed by RhCl(PPh3)3 and leads to α-triethylsilyl enals. Addition of aryl Grignard reagents takes place to give secondary allylic alcohols which are easily converted to 1,3-disubstituted allenes.
Keywords
Reduction , rhodium and compounds , Allenes , elimination reactions
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1644061
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