Title of article
The highly enantioselective transformation of silylketenes into α-silylthioesters catalysed by cinchona alkaloids
Author/Authors
Blake، نويسنده , , Alexander J and Friend، نويسنده , , Christopher L and Outram، نويسنده , , Robert J and Simpkins، نويسنده , , Nigel S and Whitehead، نويسنده , , Andrew J، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
5
From page
2877
To page
2881
Abstract
The reaction of silylketenes with thiophenol, mediated by cinchona alkaloid catalysts, proceeds to give α-silylthioester products in good chemical yield and with enantiomeric excess values in the range 79–93%. The absolute configuration of one of the thioester products was determined by X-ray diffraction.
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1644332
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