Title of article
Indium hydride: a novel radical initiator in the reduction of organic halides with tributyltin hydride
Author/Authors
Inoue، نويسنده , , Katsuyuki and Sawada، نويسنده , , Akemi and Shibata، نويسنده , , Ikuya and Baba، نويسنده , , Akio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
4661
To page
4663
Abstract
Dichloroindium hydride (Cl2InH), which was generated in situ by transmetallation between tributyltin hydride and indium trichloride, acted as a novel radical initiator for the reduction of organic halides with tributyltin hydride. The reaction was revealed to proceed through a radical process under non-oxygen conditions at room temperature, and to be applicable to intramolecular radical cyclizations.
Keywords
indium and compounds , Transmetallation , Catalysis , radicals and radical reactions
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1645728
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