• Title of article

    Influence of N-substituted lactams on acyclic free radical based hydrogen transfer

  • Author/Authors

    Guindon، نويسنده , , Yvan and Bencheqroun، نويسنده , , Mohammed، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    6041
  • To page
    6044
  • Abstract
    anti Relative stereochemistry is achieved in the hydrogen-transfer reaction of a lactam adjacent to the carbon-centered radical. The sense of diastereoselectivity is reversed using N-substituted lactams, and optimal results favoring syn reduced products are obtained with an α-methylbenzyl group and a Boc group.
  • Keywords
    N-substituted lactams , Free radical , Hydrogen transfer , diastereoselectivity
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1646741