Title of article
High-speed microwave-promoted Mitsunobu inversions. Application toward the deracemization of sulcatol
Author/Authors
Steinreiber، نويسنده , , Andreas and Stadler، نويسنده , , Alexander and Mayer، نويسنده , , Sandra F and Faber، نويسنده , , Kurt and Kappe، نويسنده , , C.Oliver، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
6283
To page
6286
Abstract
An enantioconvergent synthesis of the aggregation pheromones (R)- and (S)-sulcatol (6-methyl-5-hepten-2-ol) is described. Key steps in the deracemization strategy are sequential combinations of enzymatic resolutions and Mitsunobu inversions. Racemization-free Mitsunobu transformations have been carried out within 5 min by microwave irradiation, providing the desired sulcatyl acetates with clean inversion of chirality.
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1646914
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