Title of article
Heterogeneous acid-catalyzed (2,5) oxonium-ene reaction for eight-membered ring formation
Author/Authors
Ohmura، نويسنده , , Hirofumi and Mikami، نويسنده , , Koichi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
5
From page
6859
To page
6863
Abstract
The (2,5) ene cyclization of cyclic allylic lactol ether 1 as a substrate gave aldehyde 3 presumably via the intermediate 2. Furthermore, ring cleavage at the CO bond of the oxolane moiety in the aldehyde 3 under reductive conditions afforded the eight-membered ring regioselectively.
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1647316
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