Title of article
On the hydroxylation of bicyclo[2.1.0]pentane using dioxiranes
Author/Authors
Curci، نويسنده , , Ruggero and DʹAccolti، نويسنده , , Lucia and Fusco، نويسنده , , Caterina، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
7087
To page
7090
Abstract
The oxidation of bicyclo[2.1.0]pentane by isolated dimethyldioxirane and by the more powerful methyl(trifluoromethyl)dioxirane, affords selectively, the corresponding endo-2 alcohol along with the 2,3-diol in high yield, and no rearrangement products; this suggests that a concerted O-insertion mechanism should be preferred over radical pathways.
Keywords
insertions , oxenoids , radicals , free-radical ‘clock’ , Dioxiranes
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1647496
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