Title of article
Stereocontrolled reduction of an oxazepinohexahydroindolo[2,3-a]quinolizine derivative: asymmetric total synthesis of (+)-tacamonine
Author/Authors
Danieli، نويسنده , , Bruno and Lesma، نويسنده , , Giordano and Passarella، نويسنده , , Daniele and Sacchetti، نويسنده , , Alessandro and Silvani، نويسنده , , Alessandra، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
7237
To page
7240
Abstract
Efficient, stereocontrolled total synthesis of the title compound is described, starting from enantiopure intermediates. A key step was the diastereoselective catalytic hydrogenation of a pentacyclic oxazepinohexahydroindolo[2,3-a]quinolizine derivative.
Keywords
Alkaloids , asymmetric synthesis , Hydrogenation , diastereoselection
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1647585
Link To Document