Title of article
Indium-mediated highly regioselective reaction of prop-2-ynyl bromides with acyl cyanides in aqueous media: a convenient synthesis of allenic and propargylic ketones
Author/Authors
Yoo، نويسنده , , Byung-Woo and Lee، نويسنده , , Sung-Jae and Choi، نويسنده , , Kwang-Hyun and Keum، نويسنده , , Sam-Rok and Ko، نويسنده , , Jae-Jung and Choi، نويسنده , , Kyung-Il and Kim، نويسنده , , Joong Hyup Kim، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
7287
To page
7289
Abstract
Indium-mediated reaction of acyl cyanides 1 with prop-2-ynyl bromides 2 in aqueous media occurs regioselectively to afford either allenic 3 or propargylic ketones 4 depending on the γ-substituent of the prop-2-ynyl bromide under the mild conditions.
Keywords
Propargylation , allenylation , acyl cyanides , indium and compounds
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1647612
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