Title of article
Eu(fod)3-catalyzed solid-phase [4+2] heterocycloadditions: an efficient asymmetric process in catalyst-recycling conditions
Author/Authors
Dujardin، نويسنده , , Gilles and Leconte، نويسنده , , Stéphane and Coutable، نويسنده , , Ludovic and Brown، نويسنده , , Eric، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
8849
To page
8852
Abstract
Under Eu(fod)3-catalyzed conditions, the endo-selective hetero Diels–Alder reaction of (S)-(+)-O-vinyl mandelate with Wang-supported benzylidenepyruvate occurred with a 93/7 facial selectivity that compares well with those observed in solution. In addition, the solid-phase sequence allowed an unprecedented reuse of the catalyst in the presence of excess dienophile in solution.
Keywords
solid-phase synthesis , Reusable Catalyst , hetero Diels–Alder reactions , chiral dienophile
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1648636
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