• Title of article

    Homo-Brook route to benzazocenols and congeners via allylsilane-derived aziridines

  • Author/Authors

    Ducray، نويسنده , , Richard and Cramer، نويسنده , , Nicolai and Ciufolini، نويسنده , , Marco A، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    9175
  • To page
    9178
  • Abstract
    We describe a concise entry to benzazocenols intermediates for mitomycinoids via a homo-Brook rearrangement–ring opening sequence of a silylated aziridine. The latter is obtained by intramolecular 1,3-dipolar cycloaddition of an azide with an allylsilane, followed by irradiation of the resulting triazoline.
  • Keywords
    allylsilanes , antitumor agents , Azides , Aziridines , Heterocycles , mitomycinoids
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1648886