• Title of article

    Stereoselective intermolecular addition of ketyl radicals generated from ketones by photoinduced electron transfer

  • Author/Authors

    Brulé، نويسنده , , Cédric and Hoffmann، نويسنده , , Norbert، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    69
  • To page
    72
  • Abstract
    Ketyl radicals were produced from ketones by photochemical electron transfer and subsequent proton transfer from tertiary amines. These radicals were stereoselectively added to (5R)-5-(−)-menthyloxy-2[5H]-furanone 1. Due to their low reactivity, the α-aminoalkyl radicals which were generated at the same time were not added to 1. The ketones were used in stoichiometric quantities.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1649033