Title of article
Toward a total synthesis of brassinosteroids; structure assessment of the Ireland–Claisen products of geranyl and neryl esters
Author/Authors
Temmem، نويسنده , , O. and Uguen، نويسنده , , D. and De Cian، نويسنده , , A. and Gruber، نويسنده , , N.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
5
From page
3169
To page
3173
Abstract
As estimated by 1H NMR analysis, thermal isomerisation of the kinetic silylenolate derived from the ester (Z)-8a proceeds with acceptable diastereo and facial selectivity, thence affording an acid having the required absolute configuration for further elaboration to brassinosteroids.
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1651326
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