Title of article
In situ tandem allylic acetate isomerisation-ring closing metathesis: 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ruthenium benzylidenes and palladium(0)–phosphine combinations
Author/Authors
Braddock، نويسنده , , D.Christopher and Matsuno، نويسنده , , Ai، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
3305
To page
3308
Abstract
The use of 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ruthenium benzylidenes as olefin metathesis pre-catalysts in conjunction with palladium(0)–phosphine combinations allows tandem in situ allylic acetate isomerisation–ring closing metathesis reactions to occur. The tandem reaction can either be performed on separate substrates in the same pot, or on substrates containing both allylic acetate and diene functionality.
Keywords
allylic isomerisation , Palladium(0) , 3-dimesityl-4 , 1 , Olefin metathesis , 5-dihydroimidazol-2-ylidene , ruthenium benzylidene
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1651411
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