• Title of article

    Asymmetric conjugate additions of TMSI promoted monoorganocuprate reagents, Li[RCuI], to various N-enoyl oxazolidinones

  • Author/Authors

    Pollock، نويسنده , , Patrick and Dambacher، نويسنده , , Jesse and Anness، نويسنده , , Robert and Bergdahl، نويسنده , , Mikael، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    5
  • From page
    3693
  • To page
    3697
  • Abstract
    Diastereoselective conjugate additions to different α,β-unsaturated N-acyl oxazolidinones using various monoorganocuprate reagents, Li[RCuI], are described. The TMSI activated conjugate addition reactions provided high yields (80–98%) and reversed major diastereomers (70–96% de) compared to the conventional copper(I)-promoted additions of Grignard reagents or the addition of Li[RCuI] to precomplexed MgBr2/imides.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1651697