Title of article
Asymmetric synthesis of stereodefined α-alkyl-γ-benzyloxymethyl-β-trimethylsilyl-γ-butyrolactones that serve as an efficient precursor for constructing carbon skeletons having a tertiary or quaternary stereogenic center
Author/Authors
Kim، نويسنده , , Kwangho and Okamoto، نويسنده , , Sentaro and Takayama، نويسنده , , Yuuki and Sato، نويسنده , , Fumie، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
4237
To page
4239
Abstract
The optically active lactone 1 can be transformed to a chiral building block or intermediate for constructing carbon skeletons containing either a tertiary or quaternary stereogenic center by taking advantage of the steric bulk as well as the reactivity of a trimethylsilyl group at the β-position of 1.
Keywords
asymmetric synthesis , Lactones , Olefination , Reduction , Titanium
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1652090
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