Title of article
Highly enantioselective Baeyer–Villiger oxidation using Zr(salen) complex as catalyst
Author/Authors
Watanabe، نويسنده , , Akira and Uchida، نويسنده , , Tatsuya and Ito، نويسنده , , Katsuji and Katsuki، نويسنده , , Tsutomu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
5
From page
4481
To page
4485
Abstract
(R,R)-Zr(salen) complex was found to serve as an efficient catalyst for asymmetric Baeyer–Villiger oxidation of pro-chiral and racemic ketones using urea·hydrogen peroxide as the terminal oxidant: for example, high enantioselectivity of 87% ee was achieved in the Baeyer–Villiger reaction of 3-phenylcyclobutanone.
Keywords
Zr(salen) complex , Baeyer–Villiger oxidation , Hydrogen peroxide , Asymmetric catalysis
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1652247
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